Gas-Liquid Chromatography of Aliphatic Ketones

Gas-liquid partition chromatography: the separation of volatile aliphatic amines and of the homologues of pyridine.

Fig. 6. Analysis of the volatile amines present in Chenopodium vulvaria L. Curve A: standard mixture ofmono-, diand tri-methylamines. Curve B: chromatogram of the amines present in an acid extract ofthe plant, showing the presence of only ammonia and trimethylamine. (Column length, 4ft.; liquid phase, hendecanol-iS% liquid paraffin (v/v); temp., 78 50; flow rate of nitrogen, 5.7 ml./min.; nitro...

Gas and Liquid Chromatography

Wine: Gas and Liquid Chromatography

From the chemical point of view, wines are aqueous alcoholic solutions containing more than 1000 components that can be present at high concentrations (g L ), but also at trace levels (ng L ). Some of these components determine the organoleptic properties of wines, while others are signi"cant for classifying their origin and/or for checking whether some adulteration has taken place. Concentrati...

Gas-liquid chromatography of hyocholic acid.

Partial derivatives of hyocholic acid were formed under the usual conditions for trifluoroacetylation of bile acids (trifluoroacetic anhydride, 35 degrees C for 20 min). Complete trifluoroacetylation of hyocholic acid was achieved at 80 degrees C for 30 min, or at 60 degrees C for 30 min when a trace of pyridine was added to the reaction mixture.

Separation of triglycerides by gas-liquid chromatography.

The parameters affecting the separation and quantification of triglycerides by gas-liquid chromatography have been investigated with the use of QF-1 and SE-30 as stationary phases and a flame ionization detector. The isothermal characteristics of a wide variety of triglycerides (carbon number 6 to 60) on both columns show that long retention volume is directly proportional to carbon number and ...